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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For NaF+ atoms 1 and 2

For NaF+ (sodium fluoride cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.0003 0.0215 0.0323 0.0139 0.0326 0.0326 0.0401 0.0475 0.0475 0.0775 0.1014 0.0490 0.0302 0.0804 0.0890 0.0408 0.0758 0.2086 0.2106 0.1807
MP3=FULL         0.0350   -0.0460       0.1077 0.0531 0.0337 0.0870         0.2192 0.1881
MP4=FULL   0.0238     0.0363       0.0528   0.1147   0.0348 0.0875   0.0466 0.0846   0.2259 0.1967
B2PLYP=FULL -0.0000 0.0133 0.0230 0.0032 0.0152 0.0144 0.0213 0.0247 0.0248 0.0334 0.0486 0.0242 0.0182 0.0338   0.0269 0.0358   0.0819 0.0702
Quadratic configuration interaction QCISD(T)=FULL         0.0365           0.1153   0.0345 0.0876   0.0469 0.0852   0.2264 0.1969
Coupled Cluster CCSD=FULL         0.0355         0.0857 0.1096 0.0524 0.0345 0.0874 0.0972 0.0468 0.0836 0.2452 0.2231 0.1918
CCSD(T)=FULL         0.4647           0.1148 0.0522 0.0344 0.0877 0.0990 0.0470 0.0851 0.2468 0.2262 0.1967
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

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