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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For LiF atoms 1 and 2

For LiF (lithium fluoride)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pCVDZ cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0002 0.0005 0.0005 0.0007 0.0027 0.0035 0.0211 -0.0018 0.0031 0.0052 0.0079 0.0013 0.0012 0.0168 0.0144 0.0262 0.0130 0.0232 0.0028 0.0058 0.0131 0.0178
MP3=FULL         0.0053   -0.0045       0.0080 0.0013 0.0013 0.0078         0.0027 0.0093 0.0141 0.0182
MP4=FULL   0.0008     0.0038       0.0035   0.0088   0.0014 0.0083   0.0317 0.0142   0.0029 0.0096 0.0159 0.0195
B2PLYP=FULL -0.0000 0.0002 0.0002 0.0002 -0.0083 0.0012 0.0065 0.0010 0.0010 0.0017 0.0026 0.0004 0.0004 -0.0049   0.0080 0.0035   0.0008 0.0028 0.0035 0.0054
Quadratic configuration interaction QCISD(T)=FULL         0.0037           0.0085   0.0014 0.0083   0.0306 0.0139   0.0028 0.0095 0.0154 0.0191
Coupled Cluster CCSD=FULL         0.0038         0.0055 0.0083 0.0013 0.0013 0.0079 0.0153 0.0295 0.0134 0.0248 0.0027 0.0092 0.0143 0.0185
CCSD(T)=FULL         0.0037           0.0089 0.0014 0.0015 0.0082 0.0158 0.0302 0.0138 0.0255 0.0028 0.0095 0.0153 0.0190
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pCVDZ cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ

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