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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For LiF+ atoms 1 and 2

For LiF+ (lithium fluoride cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.0002 0.0002 0.0002 0.0006 0.0055 0.0055 0.0248 0.0101 0.0101 0.0097 0.0271 0.0021 0.0019 0.0233 0.0216 0.0595 0.0456 0.0413 0.1089 0.0660
MP3=FULL         0.3484   0.0174       0.0287 0.0020 0.0020 0.0244         0.1186 0.0693
MP4=FULL   0.0009     0.0053       0.0107   0.0295   0.0019 0.0244   0.0629 0.0491   0.1235 0.0706
B2PLYP=FULL -0.0001 0.0002 0.0000 0.0000 0.0021 0.0016 0.0093 0.0031 0.0034 0.0027 0.0083 0.0006 0.0005 -0.3529   0.0178 0.0134   0.0394 0.0199
Quadratic configuration interaction QCISD(T)=FULL         0.0053           0.0296   0.0021 0.0236   0.0630 0.0491   0.1243 0.0706
Coupled Cluster CCSD=FULL         0.0056         0.0099 0.0288 0.0017 0.0020 0.0240 0.0237 0.0667 0.0487 0.0456 0.1229 0.0696
CCSD(T)=FULL         0.0059           0.0295 0.0020 0.0021 0.0236 0.0239 0.0631 0.0484 0.0470 0.1241 0.0705
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

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