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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For GeCl atoms 1 and 2

For GeCl (Germanium monochloride)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0013 0.0005 0.0015 0.0004 0.0060 0.0060 0.0063 0.0088 0.0088 0.0271 0.0182 -0.0009 0.0023 0.0103 0.0103 0.0034 0.0152 0.0161 0.0040 0.0194
MP3=FULL         0.0042   0.0124                          
B2PLYP=FULL 0.0010 0.0002 0.0005 0.0003 0.0022 0.0022 0.0024 0.0030 0.0030 0.0097 0.0063 -0.0003 0.0008 0.0030   0.0010 0.0044   0.0012 0.0059
Quadratic configuration interaction QCISD(T)=FULL         0.0048           0.0142   0.0021 0.0079   0.0035 0.0121   0.0039 0.0175
Coupled Cluster CCSD=FULL         0.0047         0.0236 0.0132 -0.0014 0.0021 0.0081 0.0080 0.0035 0.0129 0.0132 0.0041 0.0177
CCSD(T)=FULL         0.0041           0.0141 -0.0014 0.0019 0.0082 0.0087 0.0033 0.0127 0.0130 0.0039 0.0174
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

geclq1.gif