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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For GeCl+ atoms 1 and 2

For GeCl+ (Germanium monochloride cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ aug-cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0013 0.0002 0.0012 -0.0003 0.0046 0.0046 0.0044 0.0079 0.0079 0.0209 0.0152 -0.0011 0.0016 0.0071 0.0100 0.0021 0.0116 0.0139 0.0117 0.0026 0.0144
MP3=FULL         0.0034   0.0037       0.0094 -0.0023 0.0012 0.0049         0.0089 0.0021 0.0114
MP4=FULL   0.0001     0.0039       0.0063   0.0139   0.0016 0.0067   0.0021 0.0111   0.0108 0.0027 0.0131
B2PLYP=FULL 0.0009 0.0001 0.0004 0.0000 0.0017 0.0017 0.0018 0.0028 0.0028 0.0068 0.0053 -0.0004 0.0005 0.0022   0.0007 0.0035   0.0037 0.0009 0.0044
Quadratic configuration interaction QCISD(T)=FULL         0.0038           0.0117   0.0016 0.0060   0.0021 0.0097   0.0109 0.0026 0.0123
Coupled Cluster CCSD=FULL         0.0035         0.0179 0.0113 -0.0016 0.0014 0.0056 0.0080 0.0018 0.0094 0.0113 0.0105 0.0023 0.0122
CCSD(T)=FULL         0.0037           0.0116 -0.0016 0.0014 0.0058 0.0081 0.0020 0.0100 0.0114 0.0097 0.0025 0.0115
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ aug-cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ

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