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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CaBr (Calcium monobromide)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.004077 -0.004390 -0.014641 -0.010135 -0.027200 -0.027200 -0.027760 -0.502763 -0.502763 -0.082751 -0.572315 -0.094991 -0.093364 -0.213201 -0.302180
MP3=FULL         -0.025249   -0.025788       -0.516940 -0.086343 -0.098931 -0.218171  
MP4=FULL   -0.004337     -0.026169       -0.476074   -0.541942   -0.101087 -0.225493  
B2PLYP=FULL -0.001344 -0.001352 -0.004567 -0.002969 -0.008340 -0.008340 -0.008504 -0.146430 -0.146430 -0.025554 -0.166794 -0.028645 -0.030494 -0.068625  
Quadratic configuration interaction QCISD(T)=FULL         -0.025986           -0.534918     -0.224382  
Coupled Cluster CCSD=FULL         -0.025421         -0.076751 -0.529595 -0.089587 -0.099656 -0.219894 -0.308531
CCSD(T)=FULL         -0.025963           -0.534744     -0.224221 -0.316368
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ