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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For GeCl2 (Germanium dichloride)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000950 -0.012586 -0.034530 -0.018874 -0.051344 -0.051345 -0.053693 -0.490763 -0.490763 -0.136971 -0.632201 -0.194017 -0.021517 -0.128558 -0.201788 -0.025806 -0.138281 -0.208050 -0.270818 -0.027149 -0.143807
MP3=FULL         -0.048302   -0.077462                       -0.253743    
MP4=FULL                                     -0.266076    
B2PLYP=FULL -0.000441 -0.003857 -0.010552 -0.005837 -0.016483 -0.016465 -0.017195 -0.147179 -0.147179 -0.043589 -0.189020 -0.058037 -0.006666 -0.038859   -0.007976 -0.041673   -0.079904 -0.008416 -0.043262
Quadratic configuration interaction QCISD(T)=FULL         -0.050473           -0.595087   -0.019796 -0.121464   -0.023970 -0.130471   -0.261860 -0.025256 -0.135585
Coupled Cluster CCSD=FULL         -0.048733         -0.126234 -0.585606 -0.172949 -0.018870 -0.117487 -0.186988 -0.022861 -0.126427 -0.192387 -0.256885 -0.024098 -0.131538
CCSD(T)=FULL         -0.050429           -0.594628 -0.176124 -0.019774 -0.121238 -0.191650 -0.023929 -0.130239 -0.197114 -0.261642 -0.025214 -0.135354
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ