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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For GeSe (Germanium monoselenide)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.001168 -0.006874 -0.021271 -0.024055 -0.065198 -0.065198 -0.066455 -0.774194 -0.774194 -0.193687 -0.866681 -0.208390 -0.018188 -0.108865 -0.158573 -0.021364 -0.117042 -0.162384 -0.022350 -0.120299
B2PLYP=FULL -0.000615 -0.002108 -0.006664 -0.007312 -0.021193 -0.021193 -0.021565 -0.232007 -0.232007 -0.062124 -0.259691 -0.062662 -0.005774 -0.033333   -0.006753 -0.035713   -0.007058 -0.036664
Quadratic configuration interaction QCISD(T)=FULL         -0.064173           -0.801311   -0.017180 -0.100573   -0.020264 -0.107995   -0.021208 -0.110950
Coupled Cluster CCSD=FULL         -0.062017         -0.179745 -0.788898 -0.180121 -0.016170 -0.096185 -0.138982 -0.019076 -0.103613 -0.142267 -0.019977 -0.106557
CCSD(T)=FULL         -0.064130           -0.800697 -0.184495 -0.017166 -0.100301 -0.143585 -0.020232 -0.107727 -0.146888 -0.021174 -0.110682
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ