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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For PSe (Phosphorus monoselenide)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.001381 -0.009311 -0.023992 -0.014807 -0.044111 -0.044111 -0.045438 -0.503077 -0.503077 -0.118120 -0.591212 -0.098927 -0.015701 -0.090063 -0.135729 -0.018161 -0.096543 -0.137549
MP3=FULL         -0.029019   -0.030128       -0.528990 -0.074051 -0.001904 -0.071148        
MP4=FULL   -0.008838     -0.042893       -0.483399   -0.568559   -0.014963 -0.088656     -0.094940  
B2PLYP=FULL -0.000445 -0.002852 -0.007414 -0.004447 -0.013811 -0.013811 -0.014211 -0.148299 -0.148299 -0.036873 -0.174390 -0.029610 -0.004904 -0.027276   -0.005654 -0.029165  
Quadratic configuration interaction QCISD(T)=FULL         -0.041987           -0.559627   -0.013768 -0.085468   -0.017101 -0.092704  
QCISD(TQ)=FULL         -0.035156   -0.045098       -0.557803   -0.015966 -0.084786 -0.128867 -0.018221 -0.092837 -0.128717
Coupled Cluster CCSD=FULL         -0.041174         -0.108938 -0.552494 -0.088953 -0.013951 -0.083605 -0.125381 -0.016248 -0.089742 -0.127081
CCSD(T)=FULL         -0.042403           -0.559356 -0.091613 -0.014652 -0.086368   -0.015649 -0.092368  
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ