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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For HS (Mercapto radical)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(D+d)Z cc-pV(T+d)Z aug-cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ cc-pCVQZ
Moller Plesset perturbation MP2=FULL -0.000356 -0.005015 -0.012594 -0.002934 -0.010143 -0.010500 -0.011173 -0.120104 -0.120328 -0.019376 -0.028160 -0.006608 -0.034438 -0.058775 -0.007519 -0.036696 -0.059368 -0.053991 -0.099590 -0.101792 -0.211547 -0.330212 -0.386695
MP3=FULL         -0.009565   -0.012261       -0.027475 -0.006023 -0.033309         -0.052313 -0.098008 -0.100236 -0.211441 -0.329846 -0.386570
MP4=FULL   -0.004713     -0.009620       -0.119783     -0.006103 -0.033950   -0.007023 -0.036248   -0.052435 -0.099059 -0.101314 -0.211745 -0.331544 -0.388890
B2PLYP=FULL -0.000113 -0.001541 -0.003832 -0.000900 -0.003079 -0.003182 -0.003385 -0.034612 -0.034678 -0.005847 -0.008338 -0.002023 -0.010326   -0.002299 -0.010972   -0.015881 -0.029268 -0.029895 -0.060472 -0.094352 -0.110119
Quadratic configuration interaction QCISD(T)=FULL         -0.009604   -0.010625         -0.006096 -0.033893   -0.007009 -0.036179   -0.052395     -0.211692   -0.388478
QCISD(TQ)=FULL         -0.009588   -0.010606         -0.006076 -0.033783 -0.058481 -0.006973 -0.036060 -0.059070   -0.098693 -0.100930   -0.331071  
Coupled Cluster CCSD=FULL         -0.009403         -0.017673 -0.027362 -0.005912 -0.033136 -0.057510 -0.006785 -0.035394 -0.058089 -0.051914 -0.097644 -0.099851 -0.210867 -0.328809 -0.385354
CCSD(T)=FULL         -0.009604           -0.027833 -0.006094 -0.033876 -0.058612 -0.007002 -0.036158 -0.059204 -0.052392 -0.098870 -0.101113 -0.211688 -0.331235 -0.388466
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(D+d)Z cc-pV(T+d)Z aug-cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ cc-pCVQZ