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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For GeF2 (Germanium difluoride)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.000973 -0.007708 -0.014179 -0.019614 -0.040103 -0.040103 -0.043110 -0.432293 -0.432293 -0.122832 -0.173751 -0.013762 -0.086683 -0.139826 -0.016927 -0.096080 -0.148530
MP4=FULL   -0.007247     -0.040966       -0.417805     -0.013223 -0.085331   -0.016410 -0.094334  
Coupled Cluster CCSD=FULL         -0.039603         -0.117608 -0.155826 -0.012510 -0.079283 -0.130701 -0.015500 -0.087980 -0.138139
CCSD(T)=FULL         -0.040799           -0.158186 -0.013035 -0.081739 -0.133411 -0.016143 -0.090442 -0.140884
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ