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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For NF (nitrogen fluoride)

Energies in Hartree
Methods with standard basis sets
3-21G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ
Moller Plesset perturbation MP2=FULL -0.003435 -0.004829 -0.004829 -0.005519 -0.036802 -0.036802 -0.003811   -0.058866 -0.004315     -0.072702 -0.104055
MP3=FULL   -0.004491   -0.016584                    
B2PLYP=FULL   -0.001408   -0.001606                    
Coupled Cluster CCSD(T)=FULL   -0.004467         -0.003464 -0.023813   -0.003948 -0.026468 -0.023813 -0.075553 -0.107143
3-21G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ