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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For NH2SH (Thiohydroxylamine)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000806 -0.007021 -0.014758 -0.004328 -0.014121 -0.014866 -0.015599 -0.139111 -0.139647 -0.030377 -0.188987 -0.046026 -0.009628 -0.050327 -0.089414 -0.011273 -0.056072 -0.090811 -0.011851 -0.058049
MP3=FULL         -0.013220   -0.014671       -0.186790 -0.045787 -0.008755 -0.049180            
MP4=FULL   -0.006553     -0.013342       -0.139579   -0.188467   -0.008859 -0.049986   -0.010504 -0.055930      
B2PLYP=FULL -0.000251 -0.002137 -0.004473 -0.001313 -0.004245 -0.004460 -0.004679 -0.040002 -0.040161 -0.009033 -0.054617 -0.013418 -0.002911 -0.014910   -0.003406 -0.016545   -0.003578 -0.017111
Quadratic configuration interaction QCISD(T)=FULL         -0.013295           -0.188130   -0.008819 -0.049841   -0.010449 -0.055769      
Coupled Cluster CCSD=FULL         -0.013023         -0.028564 -0.186342 -0.045619 -0.008589 -0.048931   -0.010174 -0.054823      
CCSD(T)=FULL         -0.013296           -0.188114 -0.046243 -0.008819 -0.049830 -0.090227 -0.010443 -0.055757 -0.091633    
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ