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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For HBS (hydrogen boron sulfide)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z aug-cc-pV(T+d)Z aug-cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.001154 -0.006418 -0.014309 -0.004375 -0.015725 -0.015914 -0.016653 -0.137746 -0.137867 -0.027484 -0.186685 -0.044268 -0.008841 -0.047609 -0.083785 -0.010372 -0.052983 -0.085082 -0.113129 -0.118425 -0.375935 -0.010857 -0.054558
MP3=FULL         -0.014934   -0.018246                         -0.116857 -0.377106    
MP4=FULL                                       -0.118561 -0.379643    
B2PLYP=FULL -0.000371 -0.001977 -0.004356 -0.001344 -0.004759 -0.004814 -0.005038 -0.039731 -0.039772 -0.008270 -0.054089 -0.013017 -0.002711 -0.014223   -0.003174 -0.015766     -0.034765 -0.107426 -0.003321 -0.016217
Quadratic configuration interaction QCISD(T)=FULL         -0.015183           -0.186271   -0.008151 -0.047523   -0.009677 -0.053207     -0.118309 -0.379223 -0.010156 -0.054876
Coupled Cluster CCSD=FULL         -0.014827         -0.025400 -0.184318 -0.044427 -0.007875 -0.046523 -0.083625 -0.009358 -0.052181 -0.084954   -0.116703 -0.376173 -0.009829 -0.053838
CCSD(T)=FULL         -0.015167           -0.186233 -0.045097 -0.008138 -0.047486 -0.085125 -0.009660 -0.053170 -0.086463   -0.118278 -0.379203 -0.010140 -0.054839
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z aug-cc-pV(T+d)Z aug-cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ