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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CF2Cl (difluorochloromethyl radical)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000427 -0.009617 -0.017069 -0.006008 -0.019417 -0.019417 -0.020979 -0.105130 -0.105130 -0.038398 -0.164367 -0.078023 -0.012430 -0.072865 -0.152278 -0.014845 -0.080532 -0.154976 -0.015529 -0.084895
MP3=FULL         -0.018082   -0.019608       -0.163110 -0.078310 -0.011133 -0.070974         -0.014124 -0.083614
MP4=FULL   -0.008943     -0.018367       -0.106208   -0.164695   -0.011323 -0.071844   -0.013723 -0.079881   -0.014387 -0.084500
B2PLYP=FULL -0.000129 -0.002867 -0.005095 -0.001790 -0.005755 -0.005755 -0.006210 -0.029959 -0.029959 -0.011265 -0.047216 -0.022340 -0.003692 -0.021263   -0.004408 -0.023427   -0.004609 -0.024663
Quadratic configuration interaction QCISD(T)=FULL         -0.018272           -0.164401   -0.011264 -0.071686   -0.013637 -0.079722   -0.014301 -0.084336
Coupled Cluster CCSD=FULL         -0.017952         -0.035663 -0.162715 -0.078204 -0.011009 -0.070654 -0.151850 -0.013332 -0.078679 -0.154579 -0.013987 -0.083264
CCSD(T)=FULL         -0.018269           -0.164380 -0.078899 -0.011260 -0.071679 -0.153698 -0.013629 -0.079719 -0.115860 -0.014292 -0.048115
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ