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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CHBr (bromomethylene)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.000337 -0.004822 -0.011689 -0.011693 -0.031433 -0.031603 -0.032402 -0.412494 -0.412646 -0.088904 -0.081812 -0.009906 -0.058115 -0.107216 -0.012224 -0.064973 -0.109682
MP3=FULL         -0.029454   -0.048474                    
Coupled Cluster CCSD(T)=FULL         -0.030153             -0.009133 -0.054878 -0.101736 -0.011376 -0.061608 -0.079694
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ