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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CH2NH (Methanimine)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000601 -0.003341 -0.003340 -0.002396 -0.007871 -0.008374 -0.008648 -0.036982 -0.037415 -0.015023 -0.044004 -0.034006 -0.004782 -0.029285 -0.057045 -0.005416 -0.033769 -0.057999 -0.005537 -0.034877
MP3=FULL         -0.007665   -0.015544       -0.045623 -0.035434 -0.004494 -0.030030         -0.005247 -0.036063
MP4=FULL   -0.003175     -0.007670       -0.038840   -0.045995   -0.004461 -0.030142   -0.005095 -0.034990   -0.005216 -0.036188
B2PLYP=FULL -0.000181 -0.000992 -0.000994 -0.000712 -0.002328 -0.002472 -0.002552 -0.010544   -0.004375 -0.012627 -0.009708 -0.001419 -0.008507   -0.001608 -0.009776   -0.001644 -0.010091
Quadratic configuration interaction QCISD(T)=FULL         -0.007653           -0.045909   -0.004438 -0.030096   -0.005070 -0.034943   -0.005191 -0.036142
Coupled Cluster CCSD=FULL         -0.007560         -0.015034 -0.045455 -0.035353 -0.004372 -0.029832 -0.059103 -0.004996 -0.034666 -0.059901 -0.005114 -0.035868
CCSD(T)=FULL         -0.007656           -0.045900 -0.035577 -0.004440 -0.030100 -0.059693 -0.005071 -0.034945 -0.060705 -0.005192 -0.036144
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ