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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For Cl (Chlorine atom)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z aug-cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ Sadlej_pVTZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.000000 -0.004192 -0.011507 -0.002528 -0.009624 -0.009624 -0.010243 -0.048624 -0.048624 -0.018947 -0.093939 -0.093939 -0.026723 -0.005668 -0.032352 -0.061817 -0.006486 -0.033456 -0.062281 -0.103211 -0.104209 -0.214106 -0.337438 -0.040783 -0.006705 -0.033739
MP3=FULL   -0.003736 -0.010677 -0.002242 -0.008935 -0.008935 -0.009534 -0.048192 -0.048192 -0.017279 -0.091632   -0.025836 -0.005029 -0.030822   -0.005783 -0.031908             -0.005989 -0.032188
MP4=FULL   -0.003900 -0.010760 -0.002359 -0.008983 -0.008983 -0.009591 -0.048561 -0.048561 -0.017353 -0.092520 -0.092520 -0.026137 -0.005095 -0.031349 -0.060995 -0.005909 -0.032470 -0.061463 -0.101525 -0.102563       -0.006116 -0.032755
B2PLYP=FULL 0.000000 -0.001274 -0.003464 -0.000767 -0.002892 -0.002892 -0.003077 -0.014019 -0.014019 -0.005670 -0.027295   -0.007844 -0.001722 -0.009643   -0.001968 -0.009963             -0.002033 -0.010044
Quadratic configuration interaction QCISD(T)=FULL         -0.008979   -0.009587       -0.092388     -0.005098 -0.031309 -0.060882 -0.005905 -0.032420 -0.061346           -0.006112 -0.032705
QCISD(TQ)=FULL         -0.008965   -0.009573       -0.092213     -0.005084 -0.031208 -0.060722 -0.005874 -0.032312 -0.061184              
Coupled Cluster CCSD=FULL   -0.003757 -0.010546 -0.002264 -0.008809 -0.008809 -0.009406 -0.048115 -0.048115 -0.016948 -0.091322 -0.091322 -0.025746 -0.004948 -0.030649 -0.059809 -0.005717 -0.031730 -0.060259 -0.100274 -0.101267       -0.005921 -0.032010
CCSD(T)=FULL   -0.003860 -0.010759 -0.002328 -0.008977 -0.008977 -0.009585 -0.048558 -0.048558 -0.017298 -0.092368 -0.092368 -0.026135 -0.005096 -0.031292 -0.060856 -0.005898 -0.032401 -0.061320 -0.101363 -0.102382 -0.213648 -0.337120   -0.006105 -0.032686
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z aug-cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ Sadlej_pVTZ daug-cc-pVDZ daug-cc-pVTZ