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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For AlGa (Aluminum Gallium)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.007669 -0.007479 -0.020240 -0.015851 -0.036002 -0.036002 -0.037522 -0.537656 -0.537656 -0.097067 -0.213690 -0.012657 -0.099328 -0.107746 -0.014051 -0.115471 -0.112745
MP3=FULL         -0.035399   -0.036925       -0.179922 -0.011347 -0.102153        
MP4=FULL   -0.007241     -0.037665       -0.526242     -0.012656     -0.014091 -0.118238  
B2PLYP=FULL -0.002845 -0.002380 -0.006437 -0.005094 -0.012202 -0.012202 -0.012689 -0.163980 -0.163980 -0.032198 -0.064781 -0.004059 -0.034096   -0.004497 -0.035296  
Quadratic configuration interaction QCISD(T)=FULL         -0.037978             -0.012501 -0.110017   -0.013899 -0.114201  
QCISD(TQ)=FULL         -0.037634   -0.039237         -0.012200 -0.107689   -0.013554    
Coupled Cluster CCSD=FULL         -0.036198         -0.093740 -0.192479 -0.011698 -0.105997 -43.624744 -0.013004 -0.110106 -0.102255
CCSD(T)=FULL         -0.037908           -0.196107 -0.012462 -0.109684 -230.716964 -0.013852 -0.113862 -0.106132
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ