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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For OCS+ (Carbonyl sulfide cation)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ aug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.001044 -0.008587 -0.016399 -0.005511 -0.018609 -0.018609 -0.019768 -0.157611 -0.157611 -0.037604 -0.011084 -0.061986 -0.068775
MP3=FULL         -0.017757   -0.023355            
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ aug-cc-pVTZ