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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For Cl2CS (Thiophosgene)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z
Moller Plesset perturbation MP2=FULL -0.001131 -0.015672 -0.038584 -0.009977 -0.036162 -0.036162 -0.038067 -0.237519 -0.237519 -0.071410 -0.100067 -0.021431 -0.116639 -0.212290 -0.025198 -0.126669 -0.216148 -0.324565
MP4=FULL   -0.014616     -0.034093       -0.237532     -0.019460 -0.114262   -0.023215 -0.124492    
Coupled Cluster CCSD=FULL         -0.033059           -0.097421 -0.018635 -0.111222 -0.206774 -0.022207 -0.121348    
CCSD(T)=FULL         -0.033852           -0.099067 -0.019275 -0.113639   -0.022955 -0.123839    
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z