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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For NHCHSH (Methanimidothioic acid)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.001258 -0.008576 -0.016327 -0.005595 -0.018844 -0.019576 -0.020457 -0.157606 -0.158141 -0.037570 -0.210987 -0.062843 -0.011902 -0.065245 -0.116581 -0.013938 -0.073463 -0.118662 -0.014463 -0.075935
MP3=FULL         -0.017834   -0.019420       -0.209481 -0.063362 -0.010848 -0.064481         -0.013338 -0.075655
MP4=FULL   -0.008058     -0.018030       -0.158931   -0.211542   -0.011004 -0.065448   -0.013045 -0.074100   -0.013566 -0.076688
B2PLYP=FULL -0.000394 -0.002606 -0.004946 -0.001695 -0.005653 -0.005863 -0.006127 -0.045311 -0.045471 -0.011142 -0.060973 -0.018252 -0.003599 -0.019269   -0.004209 -0.021607   -0.004366 -0.022319
Quadratic configuration interaction QCISD(T)=FULL         -0.017971           -0.211146   -0.010950 -0.065282   -0.012973 -0.073919   -0.013492 -0.076507
Coupled Cluster CCSD=FULL         -0.017616         -0.035611 -0.209065 -0.063213 -0.010659 -0.064193 -0.117028 -0.012633 -0.072786 -0.119132 -0.013140 -0.075373
CCSD(T)=FULL         -0.017972           -0.211120 -0.063985 -0.010947 -0.065266 -0.118816 -0.012966 -0.073902 -0.120947 -0.013484 -0.076491
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ