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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For B (Boron atom)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ
Moller Plesset perturbation MP2=FULL -0.000438 -0.001193 -0.001193 -0.001202 -0.003740 -0.003740 -0.003838 -0.016473 -0.016473 -0.003035 -0.017417 -0.017417 -0.014788 -0.001025 -0.007240 -0.021354 -0.001084 -0.007672 -0.021412 -0.007240 -0.033021 -0.043426
MP3=FULL         -0.003771   -0.003890                              
MP4=FULL -0.000330 -0.001093 -0.001093 -0.001092 -0.003747 -0.003747 -0.003845 -0.017474 -0.017474 -0.002930 -0.019092 -0.018488 -0.015914 -0.000895 -0.007337 -0.022737 -0.001328 -0.008438 -0.022797      
B2PLYP=FULL   -0.000365     -0.001129   -0.001157                              
Coupled Cluster CCSD=FULL -0.000272 -0.001006 -0.001006 -0.001002 -0.003627 -0.003627 -0.003718 -0.017185 -0.017199 -0.002803 -0.018154 -0.018154 -0.015700 -0.000825 -0.007080 -0.022325 -0.000877 -0.007561 -0.022384      
CCSD(T)=FULL -0.000272 -0.001041 -0.001041 -0.001037 -0.003721 -0.003721 0.000000 -0.017366 -0.017380 -0.002903 -0.018424 -0.018424 -0.015859 -0.000842 -0.007265 -0.022664 -0.000912 -0.007752 -0.022724 -0.007281 -0.035441 -0.045757
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ