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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CF3Br (Bromotrifluoromethane)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000504 -0.010642 -0.017547 -0.015528 -0.040164 -0.040164 -0.042504 -0.469972 -0.469972 -0.109868 -0.535462 -0.133933 -0.016800 -0.099305 -0.202688 -0.020978 -0.112530 -0.207370 -0.022249 -0.119355
MP3=FULL         -0.037671   -0.078851       -0.487108 -0.124667 -0.015028 -0.092695            
MP4=FULL   -0.009948     -0.038786       -0.447687   -0.511239   -0.015710 -0.097331   -0.019882 -0.110796      
B2PLYP=FULL -0.000151 -0.003143 -0.005258 -0.004559 -0.012137 -0.012137 -0.012814 -0.137085 -0.137085 -0.033266 -0.156236 -0.038775 -0.005019 -0.029109   -0.006263 -0.032839   -0.006638 -0.034770
Quadratic configuration interaction QCISD(T)=FULL         -0.038491           -0.504355   -0.015513 -0.095884   -0.019605 -0.109229      
Coupled Cluster CCSD=FULL         -0.037757         -0.103243 -0.499326 -0.127189 -0.015034 -0.093800   -0.019005 -0.107123      
CCSD(T)=FULL         -0.038472           -0.504204 -0.129276 -0.015505 -0.095818   -0.019586 -0.109160      
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ