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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For TiF4 (Titanium tetrafluoride)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ aug-cc-pVDZ aug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.039094 -0.155309 -0.155309 -0.158487 -0.216978 -0.216978 -0.232472 -0.469558 -0.469558 -0.278574 -0.286932 -0.199760 -0.350100 -0.227398 -0.364176
MP3=FULL         -0.226909   -0.241361       -0.294302 -0.209815 -0.359569    
MP4=FULL   -0.161549     -0.233009       -0.493054     -0.213271 -0.379444 -0.245128 -0.393500
B2PLYP=FULL -0.012239 -0.048283 -0.048283 -0.049793 -0.068647 -0.068647 -0.073824 -0.142237 -0.142237 -0.087602 -0.088697 -0.063395 -0.109496 -0.072479 -0.113619
Quadratic configuration interaction QCISD(T)=FULL         -0.231226             -0.212677 -0.373439 -0.242603 -0.387462
QCISD(TQ)=FULL         -0.233486   -0.276314             -0.271177  
Coupled Cluster CCSD=FULL         -0.225376           -0.293650 -0.207726 -0.360716 -0.235799 -0.374417
CCSD(T)=FULL         -0.231717           -0.299643 -0.213478 -0.372823 -0.242961 -0.386863
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ aug-cc-pVDZ aug-cc-pVTZ