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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CH3BO (Borane, methyloxo-)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.001097 -0.004727 -0.004727 -0.003676 -0.012749 -0.013312 -0.013927 -0.054877 -0.055300 -0.024065 -0.050294 -0.006862 -0.042472 -0.083591 -0.008458 -0.049780 -0.085486
MP3=FULL         -0.012609   -0.013818       -0.052686 -0.006469 -0.043787        
MP4=FULL   -0.004560     -0.012706       -0.057768     -0.006472 -0.043871   -0.008081 -0.051834  
B2PLYP=FULL -0.000336 -0.001415 -0.001415 -0.001103 -0.003792 -0.003954 -0.004137 -0.015702 -0.015829 -0.007046 -0.014402 -0.002047 -0.012378   -0.002535 -0.014466  
Quadratic configuration interaction QCISD(T)=FULL         -0.012669             -0.006432 -0.043904   -0.008066 -0.051888  
QCISD(TQ)=FULL         -0.012671   -0.013862         -0.006429   -0.087940 -0.008074 -0.051590 -0.089961
Coupled Cluster CCSD=FULL         -0.012525         -0.024330 -0.052670 -0.006343 -0.043549 -0.086994 -0.007985 -0.051524 -0.089036
CCSD(T)=FULL         -0.012670           -0.052961 -0.006432 -0.043916 -0.087795 -0.008070 -0.051902 -0.089810
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ