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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For H2CS- (thioformaldehyde anion)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.000646 -0.006695 -0.014398 -0.004287 -0.015116 -0.015475 -0.016200 -0.138642 -0.138938 -0.027607 -0.187945 -0.045159 -0.009019 -0.049623 -0.086707 -0.010296 -0.054787 -0.087984
MP3=FULL         -0.014278   -0.015332       -0.185596 -0.045096 -0.008127 -0.048573        
MP4=FULL   -0.006286     -0.014480       -0.139192   -0.187564   -0.008287 -0.049573   -0.009600 -0.054983  
B2PLYP=FULL -0.000208 -0.002052 -0.004374 -0.001310 -0.004549 -0.004651 -0.004868 -0.039919 -0.040009 -0.008237 -0.054361 -0.013218 -0.002743 -0.014725   -0.003126 -0.016197  
Quadratic configuration interaction QCISD(T)=FULL         -0.014419           -0.187176   -0.008249 -0.049379   -0.009510 -0.054734  
Coupled Cluster CCSD=FULL         -0.014133         -0.025511 -0.185322 -0.045037 -0.008007 -0.048428 -0.086266 -0.009216 -0.053728  
CCSD(T)=FULL         -0.014418           -0.187152 -0.045655 -0.008237 -0.049357 -0.087725 -0.009498 -0.054707 -0.089000
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ