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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For GeCl+ (Germanium monochloride cation)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ aug-cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000909 -0.008046 -0.022261 -0.016037 -0.039663 -0.039663 -0.041169 -0.440726 -0.440726 -0.112715 -0.534727 -0.166829 -0.014921 -0.093315 -0.138687 -0.017703 -0.099662 -0.142362 -0.170652 -0.018660 -0.103641
MP3=FULL         -0.038079   -0.039535       -0.472080 -0.137768 -0.013112 -0.081515         -0.156669 -0.016482 -0.090547
MP4=FULL   -0.007614     -0.040123       -0.425380   -0.514042   -0.014200 -0.091420   -0.016970 -0.097494   -0.167671 -0.017911 -0.101291
B2PLYP=FULL -0.000402 -0.002464 -0.006869 -0.004946 -0.012868 -0.012868 -0.013325 -0.132606 -0.132606 -0.036302 -0.160547 -0.050053 -0.004695 -0.028415   -0.005548 -0.030261   -0.050742 -0.005842 -0.031411
Quadratic configuration interaction QCISD(T)=FULL         -0.039843           -0.500123   -0.013961 -0.087738   -0.016660 -0.093564   -0.163648 -0.017578 -0.097220
Coupled Cluster CCSD=FULL         -0.038452         -0.105082 -0.491901 -0.146997 -0.013266 -0.084515 -0.126412 -0.015842 -0.090314 -0.129594 -0.159875 -0.016725 -0.093982
CCSD(T)=FULL         -0.039803           -0.499678 -0.149757 -0.013946 -0.087538 -0.129915 -0.016636 -0.093365 -0.133129 -0.163459 -0.017553 -0.097023
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ aug-cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ