CCCBDB Elelctron affinities page 2

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composite	G2	1.198
	G3	1.285
	G3B3	1.288
	G4	1.239
	CBS-Q	1.212

		STO-3G	3-21G	3-21G*	6-31G	6-31G*	6-31G**	6-31+G**	6-311G*	6-311G**	6-31G(2df,p)	6-311+G(3df,2p)	TZVP	cc-pVDZ	cc-pVTZ	cc-pVQZ	aug-cc-pVDZ	aug-cc-pVTZ	aug-cc-pVQZ	daug-cc-pVTZ
hartree fock	HF	-6.165	0.532	0.409	0.654	0.532	0.525	0.770	0.643	0.636	0.506		0.613	0.453	0.548	0.690	0.785	0.770	0.766	0.770
hartree fock	ROHF		0.552	0.497	0.674	0.619	0.611	0.862	0.731	0.723			0.717	0.566	0.683	0.827	0.905	0.905	0.903
density functional	LSDA	-5.085	3.310	1.368	1.572	1.502	1.501	1.866	1.697	1.699	1.505		1.672	1.431	1.595		1.899	1.893
	BLYP	-5.731	0.645	0.566	0.787	0.712	0.709	1.128	0.914	0.913	0.711		0.881	0.633	0.794
	B1B95	-5.488		0.758	0.959	0.879	0.879	1.182	1.018	1.016	0.871		0.992	0.811	0.922		1.214	1.200
	B3LYP	-5.526	0.859	0.773	0.990	0.907	0.903	1.258	1.080	1.078	0.902		1.051	0.833	0.974	1.153	1.290	1.279	1.276
	B3LYPultrafine					0.907								0.832	0.974		1.290	1.279
	B3PW91	-5.364	1.081	0.991	1.179	1.097	1.095	1.369	1.233	1.231	1.088		1.209	1.032	1.149
	mPW1PW91	-5.373	1.082	0.989	1.179	1.095	1.092	1.362	1.225	1.222	1.085		1.199	1.029	1.140		1.393	1.380
	M06-2X	-5.539	0.828	0.737	0.956	0.863	0.859	1.169	1.034	1.032	0.874	1.183	1.003	0.789	0.917		1.210	1.190
	PBEPBE	-5.490	0.990	0.907	1.108	1.035	1.033	1.373	1.195	1.193	1.031		1.164	0.960	1.096		1.410	1.401
	PBEPBEultrafine					1.035								0.959	1.096		1.410	1.401
	PBE1PBE	-5.431		0.969	1.166	1.082	1.082	1.356	1.214	1.211	1.073		1.188	1.014	1.127		1.386	1.374
	HSEh1PBE	-5.435	1.046	0.956	1.151	1.068	1.065		1.205	1.203	1.059		1.179	1.001	1.115		1.383	1.369
	TPSSh					1.066		1.322			1.055				1.097
	wB97X-D			0.845		0.950		1.221		1.064			1.052	0.796	1.010			1.245
	B97D3		0.878			0.888		1.174		1.015		1.183	1.000		0.965			1.229		1.256
		STO-3G	3-21G	3-21G*	6-31G	6-31G*	6-31G**	6-31+G**	6-311G*	6-311G**	6-31G(2df,p)	6-311+G(3df,2p)	TZVP	cc-pVDZ	cc-pVTZ	cc-pVQZ	aug-cc-pVDZ	aug-cc-pVTZ	aug-cc-pVQZ	daug-cc-pVTZ
Moller Plesset perturbation	MP2	-6.383	0.490	0.474	0.644	0.625	0.624	0.931	0.767	0.771	0.834		0.798	0.678	0.930	1.132	1.172	1.228	1.244
	MP2=FULL	-6.405	0.489	0.470	0.643	0.622	0.620	0.927	0.763	0.766	0.830		0.791	0.677	0.924	1.117	1.170	1.222	1.229
	ROMP2	-6.398		0.477	0.635	0.628	0.628	0.936	0.769	0.774	0.855		0.807	0.693	0.954		1.193
	MP3					0.596
	MP3=FULL					0.592		0.904
	MP4		0.417							0.732			0.765	0.648	0.954		1.185	1.263
	MP4=FULL		0.416			0.575				0.728				0.645	0.946		1.182	1.255
	B2PLYP					0.732
Configuration interaction	CID		0.404	0.393	0.567	0.546			0.693
Configuration interaction	CISD		0.405	0.399	0.569	0.551			0.698
		STO-3G	3-21G	3-21G*	6-31G	6-31G*	6-31G**	6-31+G**	6-311G*	6-311G**	6-31G(2df,p)	6-311+G(3df,2p)	TZVP	cc-pVDZ	cc-pVTZ	cc-pVQZ	aug-cc-pVDZ	aug-cc-pVTZ	aug-cc-pVQZ	daug-cc-pVTZ
Quadratic configuration interaction	QCISD		0.397	0.400	0.563	0.554	0.550	0.867	0.705	0.703	0.793		0.735	0.620	0.900		1.128	1.186
Quadratic configuration interaction	QCISD(T)					0.558							0.744	0.625	0.936		1.162	1.242
Coupled Cluster	CCD		0.396	0.391	0.561	0.548	0.545	0.859	0.698	0.697	0.781		0.728	0.611	0.886		1.120	1.177
	CCSD					0.553							0.734	0.619	0.899	1.094	1.127	1.187	1.196
	CCSD=FULL					0.551							0.729	0.617	0.895	1.083	1.124	1.182	1.184
	CCSD(T)					0.558							0.744	0.625	0.936	1.147	1.162	1.243	1.259
	CCSD(T)=FULL					0.555							0.737	0.623	0.930	1.134	1.159	1.236	1.245
		STO-3G	3-21G	3-21G*	6-31G	6-31G*	6-31G**	6-31+G**	6-311G*	6-311G**	6-31G(2df,p)	6-311+G(3df,2p)	TZVP	cc-pVDZ	cc-pVTZ	cc-pVQZ	aug-cc-pVDZ	aug-cc-pVTZ	aug-cc-pVQZ	daug-cc-pVTZ

		CEP-31G	CEP-31G*	CEP-121G	CEP-121G*	LANL2DZ	SDD	cc-pVTZ-PP	aug-cc-pVTZ-PP	Def2TZVPP
hartree fock	HF	0.689	0.544	0.789	0.666	0.566	0.452			0.603
density functional	B3LYP	1.078	0.987	1.139	1.057	0.924	0.778			1.040
density functional	PBEPBE									1.154
Moller Plesset perturbation	MP2	0.666	0.719	0.797	0.852	0.488	0.401			0.994

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Calculated Electron Affininty for SiH (Silylidyne)