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	hartrees
Energy at 0K	-678.886593
Energy at 298.15K	-678.890504
HF Energy	-678.101178
Nuclear repulsion energy	272.429731

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3269	3080	20.09
2	A'	1444	1360	73.66
3	A'	1194	1125	202.94
4	A'	924	870	181.95
5	A'	826	779	72.45
6	A'	558	526	102.74
7	A'	469	442	55.72
8	A'	372	351	43.70
9	A'	261	246	0.38
10	A"	3380	3185	9.20
11	A"	1029	970	223.14
12	A"	841	793	0.99
13	A"	458	431	0.00
14	A"	368	347	16.96
15	A"	201	189	0.84

Atom	x (Å)	y (Å)	z (Å)
P1	-0.024	0.123	0.000
C2	-0.492	1.664	0.000
F3	1.471	-0.411	0.000
F4	-0.492	-0.697	1.251
F5	-0.492	-0.697	-1.251
H6	-0.526	2.203	-0.935
H7	-0.526	2.203	0.935

	P1	C2	F3	F4	F5	H6	H7
P1		1.6106	1.5877	1.5674	1.5674	2.3351	2.3351
C2	1.6106		2.8569	2.6723	2.6723	1.0799	1.0799
F3	1.5877	2.8569		2.3452	2.3452	3.4201	3.4201
F4	1.5674	2.6723	2.3452		2.5018	3.6321	2.9177
F5	1.5674	2.6723	2.3452	2.5018		2.9177	3.6321
H6	2.3351	1.0799	3.4201	3.6321	2.9177		1.8705
H7	2.3351	1.0799	3.4201	2.9177	3.6321	1.8705

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	119.113	P1	C2	H7	119.113
C2	P1	F3	126.573	C2	P1	F4	114.456
C2	P1	F5	114.456	F3	P1	F4	96.024
F3	P1	F5	96.024	F4	P1	F5	105.892
H6	C2	H7	119.997

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP2=FULL/6-31G*

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP2=FULL/6-31G*

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)