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	hartrees
Energy at 0K	-540.072571
Energy at 298.15K
HF Energy	-539.621553
Nuclear repulsion energy	106.395154

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	889	838	107.23	6.72	0.30	0.46
2	A₁	346	326	11.47	1.06	0.67	0.80
3	B₂	891	839	158.44	5.58	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.568
F2	1.224	-0.474
F3	-1.224	-0.474

	P1	F2	F3
P1		1.6075	1.6075
F2	1.6075		2.4478
F3	1.6075	2.4478

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: MP2=FULL/6-31G*

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: MP2=FULL/6-31G*

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)