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All results from a given calculation for SeF2 (Selenium difluoride)

using model chemistry: B2PLYP=FULL/6-31G*

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes C2V 1A1
Energy calculated at B2PLYP=FULL/6-31G*
 hartrees
Energy at 0K-2598.387082
Energy at 298.15K 
HF Energy-2598.221483
Nuclear repulsion energy201.837926
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at B2PLYP=FULL/6-31G*
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1 728 690 36.91 10.35 0.15 0.26
2 A1 257 244 5.52 1.50 0.71 0.83
3 B2 715 678 73.11 6.34 0.75 0.86

Unscaled Zero Point Vibrational Energy (zpe) 849.8 cm-1
Scaled (by 0.9484) Zero Point Vibrational Energy (zpe) 805.9 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at B2PLYP=FULL/6-31G*
ABC
0.49677 0.25660 0.16920

See section I.F.4 to change rotational constant units
Geometric Data calculated at B2PLYP=FULL/6-31G*

Point Group is C2v

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
Se1 0.000 0.000 0.397
F2 0.000 1.315 -0.751
F3 0.000 -1.315 -0.751

Atom - Atom Distances (Å)
  Se1 F2 F3
Se11.74551.7455
F21.74552.6298
F31.74552.6298

picture of Selenium difluoride state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
F2 Se1 F3 97.759
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability