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	hartrees
Energy at 0K	-126.059301
Energy at 298.15K
HF Energy	-125.452429
Nuclear repulsion energy	151.435365

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	595	575	0.00	25.51	0.01	0.03
2	A₁'	569	550	0.00	5.85	0.71	0.83
3	A₂"	843	814	265.11	0.00	0.00	0.00
4	A₂"	424	409	59.61	0.00	0.00	0.00
5	E'	819	792	201.93	2.15	0.75	0.86
5	E'	819	792	201.93	2.15	0.75	0.86
6	E'	388	375	51.01	2.27	0.75	0.86
6	E'	388	375	51.01	2.27	0.75	0.86
7	E'	114	111	1.17	1.17	0.75	0.86
7	E'	114	111	1.17	1.17	0.75	0.86
8	E"	370	358	0.00	4.17	0.75	0.86
8	E"	370	358	0.00	4.17	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.714	0.000
F3	1.485	-0.857	0.000
F4	-1.485	-0.857	0.000
F5	0.000	0.000	1.729
F6	0.000	0.000	-1.729

	P1	F2	F3	F4	F5	F6
P1		1.7143	1.7143	1.7143	1.7289	1.7289
F2	1.7143		2.9693	2.9693	2.4347	2.4347
F3	1.7143	2.9693		2.9693	2.4347	2.4347
F4	1.7143	2.9693	2.9693		2.4347	2.4347
F5	1.7289	2.4347	2.4347	2.4347		3.4577
F6	1.7289	2.4347	2.4347	2.4347	3.4577

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2/CEP-31G

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2/CEP-31G

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)