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	hartrees
Energy at 0K	-474.530816
Energy at 298.15K
HF Energy	-474.291042
Nuclear repulsion energy	76.449139

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	3146	3037	14.61	166.45	0.12	0.22
2	A₁	1753	1692	277.59	0.78	0.36	0.53
3	A₁	1441	1391	4.73	13.51	0.56	0.72
4	A₁	800	772	2.90	30.67	0.36	0.53
5	B₁	793	765	136.29	3.43	0.75	0.86
6	B₁	362	350	7.14	0.01	0.75	0.86
7	B₂	3251	3138	0.17	92.77	0.75	0.86
8	B₂	990	956	0.01	0.37	0.75	0.86
9	B₂	352	340	7.33	0.67	0.75	0.86

Atom	y (Å)	z (Å)
C1	0.000	-1.811
C2	0.000	-0.467
S3	0.000	1.151
H4	0.940	-2.370
H5	-0.940	-2.370

	C1	C2	S3	H4	H5
C1		1.3439	2.9618	1.0942	1.0942
C2	1.3439		1.6179	2.1228	2.1228
S3	2.9618	1.6179		3.6444	3.6444
H4	1.0942	2.1228	3.6444		1.8810
H5	1.0942	2.1228	3.6444	1.8810

atom1	atom2	atom3	angle		atom1	atom2	atom3	angle
C1	C2	S3	180.000		C2	C1	H4	120.735
C2	C1	H5	120.735		H4	C1	H5	118.530

All results from a given calculation for CH₂CS (Thioketene)

using model chemistry: MP2/SDD

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for CH2CS (Thioketene)

using model chemistry: MP2/SDD

States and conformations

All results from a given calculation for CH₂CS (Thioketene)