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	hartrees
Energy at 0K	-679.042763
Energy at 298.15K	-679.046468
HF Energy	-678.151279
Nuclear repulsion energy	267.870933

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3216	3084	17.42
2	A'	1367	1311	52.41
3	A'	1132	1086	209.74
4	A'	848	813	153.40
5	A'	770	738	103.16
6	A'	501	481	53.26
7	A'	437	419	53.08
8	A'	327	313	36.86
9	A'	236	226	1.13
10	A"	3343	3206	10.24
11	A"	955	916	196.02
12	A"	811	778	1.55
13	A"	436	418	0.19
14	A"	344	330	16.83
15	A"	210	201	1.56

Atom	x (Å)	y (Å)	z (Å)
P1	-0.025	0.135	0.000
C2	-0.504	1.699	0.000
F3	1.488	-0.449	0.000
F4	-0.504	-0.702	1.272
F5	-0.504	-0.702	-1.272
H6	-0.466	2.231	-0.950
H7	-0.466	2.231	0.950

	P1	C2	F3	F4	F5	H6	H7
P1		1.6357	1.6218	1.5958	1.5958	2.3437	2.3437
C2	1.6357		2.9293	2.7166	2.7166	1.0894	1.0894
F3	1.6218	2.9293		2.3767	2.3767	3.4506	3.4506
F4	1.5958	2.7166	2.3767		2.5438	3.6797	2.9512
F5	1.5958	2.7166	2.3767	2.5438		2.9512	3.6797
H6	2.3437	1.0894	3.4506	3.6797	2.9512		1.8990
H7	2.3437	1.0894	3.4506	2.9512	3.6797	1.8990

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	117.229	P1	C2	H7	117.229
C2	P1	F3	128.121	C2	P1	F4	114.415
C2	P1	F5	114.415	F3	P1	F4	95.234
F3	P1	F5	95.234	F4	P1	F5	105.696
H6	C2	H7	121.284

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP2/aug-cc-pVDZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP2/aug-cc-pVDZ

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)