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All results from a given calculation for HSiF (fluorosilylene)

using model chemistry: B97D3/aug-cc-pVTZ

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes CS 1A'
Energy calculated at B97D3/aug-cc-pVTZ
 hartrees
Energy at 0K-389.932200
Energy at 298.15K 
HF Energy-389.932200
Nuclear repulsion energy47.384066
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at B97D3/aug-cc-pVTZ
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A' 1889 1860 408.72 251.53 0.36 0.53
2 A' 836 824 63.33 15.66 0.45 0.62
3 A' 788 776 113.88 8.48 0.72 0.84

Unscaled Zero Point Vibrational Energy (zpe) 1756.5 cm-1
Scaled (by 0.9847) Zero Point Vibrational Energy (zpe) 1729.6 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at B97D3/aug-cc-pVTZ
ABC
7.34664 0.53960 0.50268

See section I.F.4 to change rotational constant units
Geometric Data calculated at B97D3/aug-cc-pVTZ

Point Group is Cs

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
Si1 0.064 -0.609 0.000
F2 0.064 1.033 0.000
H3 -1.479 -0.779 0.000

Atom - Atom Distances (Å)
  Si1 F2 H3
Si11.64181.5529
F21.64182.3807
H31.55292.3807

picture of fluorosilylene state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
F2 Si1 H3 96.317
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at B97D3/aug-cc-pVTZ Charges (e)
Number Element Mulliken CHELPG AIM ESP
1 Si 0.581      
2 F -0.449      
3 H -0.132      


Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section VII.A.3)
  x y z Total
  -0.152 -0.999 0.000 1.011
CHELPG        
AIM        
ESP        


Electric Quadrupole moment
Quadrupole components in D Å
Primitive
 xyz
x -20.873 0.670 0.000
y 0.670 -20.335 0.000
z 0.000 0.000 -16.276
Traceless
 xyz
x -2.567 0.670 0.000
y 0.670 -1.761 0.000
z 0.000 0.000 4.328
Polar
3z2-r28.655
x2-y2-0.538
xy0.670
xz0.000
yz0.000


Polarizabilities
Components of the polarizability tensor.
Units are Å3 (Angstrom cubed)
Change units.
  x y z
x 5.756 0.097 0.000
y 0.097 4.758 0.000
z 0.000 0.000 4.606


<r2> (average value of r2) Å2
<r2> 29.651
(<r2>)1/2 5.445