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	hartrees
Energy at 0K	-1719.382076
Energy at 298.15K	-1719.383249
Nuclear repulsion energy	343.267172

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A₁	545	496	36.85
2	A₁	281	256	2.16
3	E	538	490	161.06
3	E	538	490	161.06
4	E	204	185	0.28
4	E	204	185	0.28

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.729
Cl2	0.000	1.818	-0.214
Cl3	1.575	-0.909	-0.214
Cl4	-1.575	-0.909	-0.214
X5	0.000	0.000	1.729

	P1	Cl2	Cl3	Cl4	X5
P1		2.0486	2.0486	2.0486	1.0000
Cl2	2.0486		3.1497	3.1497	2.6615
Cl3	2.0486	3.1497		3.1497	2.6615
Cl4	2.0486	3.1497	3.1497		2.6615
X5	1.0000	2.6615	2.6615	2.6615

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
Cl2	P1	Cl3	100.481	Cl2	P1	Cl4	100.481
Cl2	P1	X5	117.420	Cl3	P1	Cl4	100.481
Cl3	P1	X5	117.420	Cl4	P1	X5	117.420

All results from a given calculation for PCl₃ (Phosphorus trichloride)

using model chemistry: HF/aug-cc-pVTZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Number	Element	Mulliken
1	P	0.673
2	Cl	-0.224
3	Cl	-0.224
4	Cl	-0.224

	x	y	z	Total
	0.000	0.000	0.634	0.634
CHELPG
AIM
ESP

<r²>	210.862
(<r²>)^1/2	14.521

All results from a given calculation for PCl3 (Phosphorus trichloride)

using model chemistry: HF/aug-cc-pVTZ

States and conformations

All results from a given calculation for PCl₃ (Phosphorus trichloride)