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	hartrees
Energy at 0K	-679.125472
Energy at 298.15K	-679.129350
HF Energy	-678.149001
Nuclear repulsion energy	275.821761

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3259	3078	21.75
2	A'	1391	1314	79.27
3	A'	1177	1112	180.64
4	A'	919	868	150.63
5	A'	829	783	59.18
6	A'	501	473	42.53
7	A'	476	450	67.01
8	A'	378	357	53.72
9	A'	272	257	0.65
10	A"	3377	3189	11.41
11	A"	1014	958	186.73
12	A"	799	754	2.73
13	A"	452	427	0.20
14	A"	366	345	13.01
15	A"	189	178	0.79

Atom	x (Å)	y (Å)	z (Å)
P1	-0.024	0.116	0.000
C2	-0.488	1.655	0.000
F3	1.453	-0.392	0.000
F4	-0.488	-0.696	1.228
F5	-0.488	-0.696	-1.228
H6	-0.504	2.190	-0.935
H7	-0.504	2.190	0.935

	P1	C2	F3	F4	F5	H6	H7
P1		1.6072	1.5618	1.5436	1.5436	2.3252	2.3252
C2	1.6072		2.8205	2.6525	2.6525	1.0777	1.0777
F3	1.5618	2.8205		2.3166	2.3166	3.3720	3.3720
F4	1.5436	2.6525	2.3166		2.4558	3.6071	2.9013
F5	1.5436	2.6525	2.3166	2.4558		2.9013	3.6071
H6	2.3252	1.0777	3.3720	3.6071	2.9013		1.8704
H7	2.3252	1.0777	3.3720	2.9013	3.6071	1.8704

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	118.677	P1	C2	H7	118.677
C2	P1	F3	125.753	C2	P1	F4	114.658
C2	P1	F5	114.658	F3	P1	F4	96.486
F3	P1	F5	96.486	F4	P1	F5	105.393
H6	C2	H7	120.407

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP2/6-31G(2df,p)

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP2/6-31G(2df,p)

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)