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	hartrees
Energy at 0K	-839.378764
Energy at 298.15K
HF Energy	-838.103945
Nuclear repulsion energy	407.594389

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	815	770	0.00	9.63	0.00	0.00
2	A₁'	670	633	0.00	1.26	0.74	0.85
3	A₂"	1019	963	347.37	0.00	0.00	0.00
4	A₂"	568	537	48.37	0.00	0.00	0.00
5	E'	1038	980	238.24	0.48	0.75	0.86
5	E'	1038	980	238.24	0.48	0.75	0.86
6	E'	534	504	36.10	0.46	0.75	0.86
6	E'	534	504	36.10	0.46	0.75	0.86
7	E'	170	161	0.23	0.21	0.75	0.86
7	E'	170	161	0.23	0.21	0.75	0.86
8	E"	505	477	0.00	0.78	0.75	0.86
8	E"	505	477	0.00	0.78	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.545	0.000
F3	1.338	-0.773	0.000
F4	-1.338	-0.773	0.000
F5	0.000	0.000	1.575
F6	0.000	0.000	-1.575

	P1	F2	F3	F4	F5	F6
P1		1.5452	1.5452	1.5452	1.5753	1.5753
F2	1.5452		2.6764	2.6764	2.2066	2.2066
F3	1.5452	2.6764		2.6764	2.2066	2.2066
F4	1.5452	2.6764	2.6764		2.2066	2.2066
F5	1.5753	2.2066	2.2066	2.2066		3.1507
F6	1.5753	2.2066	2.2066	2.2066	3.1507

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2/6-31G(2df,p)

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2/6-31G(2df,p)

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)