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	hartrees
Energy at 0K	-675.054192
Energy at 298.15K	-675.058029
HF Energy	-674.501382
Nuclear repulsion energy	264.596020

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)
1	A'	3231	3162
2	A'	1466	1435
3	A'	1173	1148
4	A'	928	908
5	A'	790	773
6	A'	665	651
7	A'	432	423
8	A'	333	326
9	A'	243	238
10	A"	3342	3271
11	A"	1053	1031
12	A"	908	889
13	A"	444	434
14	A"	348	341
15	A"	174	170

Atom	x (Å)	y (Å)	z (Å)
P1	-0.031	0.139	0.000
C2	-0.496	1.719	0.000
F3	1.504	-0.431	0.000
F4	-0.496	-0.723	1.293
F5	-0.496	-0.723	-1.293
H6	-0.585	2.247	-0.939
H7	-0.585	2.247	0.939

	P1	C2	F3	F4	F5	H6	H7
P1		1.6471	1.6376	1.6225	1.6225	2.3734	2.3734
C2	1.6471		2.9366	2.7639	2.7639	1.0808	1.0808
F3	1.6376	2.9366		2.3999	2.3999	3.5240	3.5240
F4	1.6225	2.7639	2.3999		2.5862	3.7169	2.9934
F5	1.6225	2.7639	2.3999	2.5862		2.9934	3.7169
H6	2.3734	1.0808	3.5240	3.7169	2.9934		1.8773
H7	2.3734	1.0808	3.5240	2.9934	3.7169	1.8773

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	119.481	P1	C2	H7	119.481
C2	P1	F3	126.765	C2	P1	F4	115.409
C2	P1	F5	115.409	F3	P1	F4	94.804
F3	P1	F5	94.804	F4	P1	F5	105.681
H6	C2	H7	120.572

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP4=FULL/3-21G

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP4=FULL/3-21G

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)