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	hartrees
Energy at 0K	-537.112322
Energy at 298.15K
HF Energy	-536.818990
Nuclear repulsion energy	103.421694

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	865	826	49.95	10.89	0.22	0.36
2	A₁	337	322	16.28	1.67	0.72	0.83
3	B₂	880	841	76.73	7.21	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.592
F2	1.250	-0.494
F3	-1.250	-0.494

	P1	F2	F3
P1		1.6560	1.6560
F2	1.6560		2.5001
F3	1.6560	2.5001

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: MP2=FULL/3-21G

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: MP2=FULL/3-21G

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)