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	hartrees
Energy at 0K	-189.176065
Energy at 298.15K	-189.186129
Nuclear repulsion energy	134.071602

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A	3302	3272	2.08
2	A	3049	3022	1.59
3	A	3003	2975	4.24
4	A	2904	2878	126.54
5	A	1534	1520	2.75
6	A	1504	1491	0.45
7	A	1502	1488	0.56
8	A	1434	1421	0.46
9	A	1219	1207	15.83
10	A	1095	1085	8.57
11	A	1026	1016	1.99
12	A	927	919	37.17
13	A	590	584	130.06
14	A	318	315	13.36
15	A	282	279	0.88
16	A	158	157	0.96
17	B	3324	3294	2.73
18	B	3050	3022	44.37
19	B	3004	2976	63.14
20	B	2884	2858	9.67
21	B	1535	1521	13.77
22	B	1494	1481	21.43
23	B	1415	1402	0.39
24	B	1409	1396	1.60
25	B	1119	1109	8.81
26	B	1094	1084	24.22
27	B	953	945	0.54
28	B	696	690	39.18
29	B	456	452	3.52
30	B	222	220	1.72

Atom	x (Å)	y (Å)	z (Å)
N1	-0.167	0.719	-0.707
N2	0.167	-0.719	-0.707
C3	0.167	1.455	0.548
C4	-0.167	-1.455	0.548
H5	-1.183	0.772	-0.902
H6	1.183	-0.772	-0.902
H7	-0.141	2.506	0.406
H8	-0.301	1.076	1.483
H9	1.264	1.437	0.677
H10	0.141	-2.506	0.406
H11	0.301	-1.076	1.483
H12	-1.264	-1.437	0.677

	N1	N2	C3	C4	H5	H6	H7	H8	H9	H10	H11	H12
N1		1.4761	1.4927	2.5101	1.0355	2.0210	2.1051	2.2234	2.1162	3.4250	2.8705	2.7865
N2	1.4761		2.5101	1.4927	2.0210	1.0355	3.4250	2.8705	2.7865	2.1051	2.2234	2.1162
C3	1.4927	2.5101		2.9295	2.0949	2.8450	1.1039	1.1126	1.1042	3.9634	2.7023	3.2290
C4	2.5101	1.4927	2.9295		2.8450	2.0949	3.9634	2.7023	3.2290	1.1039	1.1126	1.1042
H5	1.0355	2.0210	2.0949	2.8450		2.8255	2.4078	2.5609	2.9863	3.7694	3.3625	2.7165
H6	2.0210	1.0355	2.8450	2.0949	2.8255		3.7694	3.3625	2.7165	2.4078	2.5609	2.9863
H7	2.1051	3.4250	1.1039	3.9634	2.4078	3.7694		1.7970	1.7860	5.0192	3.7666	4.1079
H8	2.2234	2.8705	1.1126	2.7023	2.5609	3.3625	1.7970		1.7963	3.7666	2.2352	2.8094
H9	2.1162	2.7865	1.1042	3.2290	2.9863	2.7165	1.7860	1.7963		4.1079	2.8094	3.8266
H10	3.4250	2.1051	3.9634	1.1039	3.7694	2.4078	5.0192	3.7666	4.1079		1.7970	1.7860
H11	2.8705	2.2234	2.7023	1.1126	3.3625	2.5609	3.7666	2.2352	2.8094	1.7970		1.7963
H12	2.7865	2.1162	3.2290	1.1042	2.7165	2.9863	4.1079	2.8094	3.8266	1.7860	1.7963

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
N1	N2	C4	115.453	N1	N2	H6	105.815
N1	C3	H7	107.389	N1	C3	H8	116.412
N1	C3	H9	108.224	N2	N1	C3	115.453
N2	N1	H5	105.815	N2	C4	H10	107.389
N2	C4	H11	116.412	N2	C4	H12	108.224
C3	N1	H5	110.607	C4	N2	H6	110.607
H7	C3	H8	108.334	H7	C3	H9	107.961
H8	C3	H9	108.246	H10	C4	H11	108.334
H10	C4	H12	107.961	H11	C4	H12	108.246

All results from a given calculation for CH₃NHNHCH₃ (dimethyl hydrazine)

using model chemistry: PBEPBE/3-21G

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Number	Element	Mulliken
1	N	-0.420
2	N	-0.420
3	C	-0.470
4	C	-0.470
5	H	0.290
6	H	0.290
7	H	0.214
8	H	0.177
9	H	0.210
10	H	0.214
11	H	0.177
12	H	0.210

	x	y	z	Total
	0.000	0.000	1.799	1.799
CHELPG
AIM
ESP

	x	y	z
x	4.852	-0.275	0.000
y	-0.275	6.352	0.000
z	0.000	0.000	4.750

<r²>	94.049
(<r²>)^1/2	9.698

All results from a given calculation for CH3NHNHCH3 (dimethyl hydrazine)

using model chemistry: PBEPBE/3-21G

States and conformations

All results from a given calculation for CH₃NHNHCH₃ (dimethyl hydrazine)