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	hartrees
Energy at 0K	-834.259083
Energy at 298.15K
HF Energy	-833.578744
Nuclear repulsion energy	392.742783

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	794	758	0.00	13.05	0.00	0.01
2	A₁'	737	703	0.00	2.80	0.70	0.82
3	A₂"	1080	1031	257.96	0.00	0.00	0.00
4	A₂"	505	482	79.61	0.00	0.00	0.00
5	E'	1099	1049	185.96	0.93	0.75	0.86
5	E'	1099	1049	185.96	0.93	0.75	0.86
6	E'	469	448	74.81	1.30	0.75	0.86
6	E'	469	448	74.81	1.30	0.75	0.86
7	E'	175	167	0.13	0.44	0.75	0.86
7	E'	175	167	0.13	0.44	0.75	0.86
8	E"	437	417	0.00	2.22	0.75	0.86
8	E"	437	417	0.00	2.22	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.607	0.000
F3	1.391	-0.803	0.000
F4	-1.391	-0.803	0.000
F5	0.000	0.000	1.630
F6	0.000	0.000	-1.630

	P1	F2	F3	F4	F5	F6
P1		1.6068	1.6068	1.6068	1.6302	1.6302
F2	1.6068		2.7830	2.7830	2.2889	2.2889
F3	1.6068	2.7830		2.7830	2.2889	2.2889
F4	1.6068	2.7830	2.7830		2.2889	2.2889
F5	1.6302	2.2889	2.2889	2.2889		3.2603
F6	1.6302	2.2889	2.2889	2.2889	3.2603

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/3-21G

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/3-21G

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)