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	hartrees
Energy at 0K	-679.101681
Energy at 298.15K	-679.105623
HF Energy	-678.207093
Nuclear repulsion energy	274.039566

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3215	3067	12.92
2	A'	1408	1344	81.16
3	A'	1174	1120	240.06
4	A'	897	856	189.76
5	A'	815	778	95.85
6	A'	537	513	86.97
7	A'	481	459	71.87
8	A'	376	359	52.95
9	A'	264	252	1.56
10	A"	3324	3171	5.36
11	A"	999	953	238.76
12	A"	821	783	0.56
13	A"	459	438	0.18
14	A"	371	354	22.02
15	A"	206	196	0.84

Atom	x (Å)	y (Å)	z (Å)
P1	-0.020	0.120	0.000
C2	-0.494	1.659	0.000
F3	1.464	-0.408	0.000
F4	-0.494	-0.693	1.238
F5	-0.494	-0.693	-1.238
H6	-0.511	2.198	-0.937
H7	-0.511	2.198	0.937

	P1	C2	F3	F4	F5	H6	H7
P1		1.6105	1.5758	1.5549	1.5549	2.3318	2.3318
C2	1.6105		2.8474	2.6583	2.6583	1.0811	1.0811
F3	1.5758	2.8474		2.3343	2.3343	3.4016	3.4016
F4	1.5549	2.6583	2.3343		2.4759	3.6181	2.9069
F5	1.5549	2.6583	2.3343	2.4759		2.9069	3.6181
H6	2.3318	1.0811	3.4016	3.6181	2.9069		1.8742
H7	2.3318	1.0811	3.4016	2.9069	3.6181	1.8742

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	118.749	P1	C2	H7	118.749
C2	P1	F3	126.667	C2	P1	F4	114.220
C2	P1	F5	114.220	F3	P1	F4	96.420
F3	P1	F5	96.420	F4	P1	F5	105.524
H6	C2	H7	120.179

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: QCISD/6-311G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: QCISD/6-311G**

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)