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All results from a given calculation for HS2 (Thiosulfeno radical)

using model chemistry: ROMP2/6-311G**

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes CS 2A"
Energy calculated at ROMP2/6-311G**
 hartrees
Energy at 0K-795.876615
Energy at 298.15K-795.877541
HF Energy-795.631292
Nuclear repulsion energy77.805479
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at ROMP2/6-311G**
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A' 2737 2737        
2 A' 935 935        
3 A' 580 580        

Unscaled Zero Point Vibrational Energy (zpe) 2125.7 cm-1
Scaled (by 1) Zero Point Vibrational Energy (zpe) 2125.7 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at ROMP2/6-311G**
ABC
10.07029 0.26095 0.25436

See section I.F.4 to change rotational constant units
Geometric Data calculated at ROMP2/6-311G**

Point Group is Cs

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
S1 0.040 1.031 0.000
S2 0.040 -0.954 0.000
H3 -1.276 -1.218 0.000

Atom - Atom Distances (Å)
  S1 S2 H3
S11.98502.6053
S21.98501.3416
H32.60531.3416

picture of Thiosulfeno radical state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
S1 S2 H3 101.342
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability