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	hartrees
Energy at 0K	-839.547981
Energy at 298.15K
HF Energy	-838.181432
Nuclear repulsion energy	404.203986

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	797	756	0.00	8.97	0.00	0.00
2	A₁'	645	612	0.00	1.56	0.74	0.85
3	A₂"	982	932	451.22	0.00	0.00	0.00
4	A₂"	568	538	67.33	0.00	0.00	0.00
5	E'	1021	969	309.99	0.45	0.75	0.86
5	E'	1021	969	309.99	0.45	0.75	0.86
6	E'	527	500	51.84	0.89	0.75	0.86
6	E'	527	500	51.84	0.89	0.75	0.86
7	E'	171	163	0.19	0.32	0.75	0.86
7	E'	171	163	0.19	0.32	0.75	0.86
8	E"	503	477	0.00	1.63	0.75	0.86
8	E"	503	477	0.00	1.63	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.558	0.000
F3	1.349	-0.779	0.000
F4	-1.349	-0.779	0.000
F5	0.000	0.000	1.589
F6	0.000	0.000	-1.589

	P1	F2	F3	F4	F5	F6
P1		1.5582	1.5582	1.5582	1.5885	1.5885
F2	1.5582		2.6988	2.6988	2.2252	2.2252
F3	1.5582	2.6988		2.6988	2.2252	2.2252
F4	1.5582	2.6988	2.6988		2.2252	2.2252
F5	1.5885	2.2252	2.2252	2.2252		3.1770
F6	1.5885	2.2252	2.2252	2.2252	3.1770

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/6-311G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/6-311G**

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)