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	hartrees
Energy at 0K	-840.118918
Energy at 298.15K
HF Energy	-838.364703
Nuclear repulsion energy	408.266942

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	818	783	0.00	10.65	0.00	0.00
2	A₁'	652	624	0.00	1.45	0.73	0.85
3	A₂"	960	919	403.45	0.00	0.00	0.00
4	A₂"	574	549	57.89	0.00	0.00	0.00
5	E'	1032	988	271.63	0.59	0.75	0.86
5	E'	1032	988	271.63	0.59	0.75	0.86
6	E'	532	509	40.85	0.49	0.75	0.86
6	E'	532	509	40.85	0.49	0.75	0.86
7	E'	173	166	0.07	0.23	0.75	0.86
7	E'	173	166	0.07	0.23	0.75	0.86
8	E"	511	489	0.00	0.84	0.75	0.86
8	E"	511	489	0.00	0.84	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.539	0.000
F3	1.333	-0.770	0.000
F4	-1.333	-0.770	0.000
F5	0.000	0.000	1.578
F6	0.000	0.000	-1.578

	P1	F2	F3	F4	F5	F6
P1		1.5390	1.5390	1.5390	1.5782	1.5782
F2	1.5390		2.6657	2.6657	2.2044	2.2044
F3	1.5390	2.6657		2.6657	2.2044	2.2044
F4	1.5390	2.6657	2.6657		2.2044	2.2044
F5	1.5782	2.2044	2.2044	2.2044		3.1565
F6	1.5782	2.2044	2.2044	2.2044	3.1565

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/cc-pVQZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/cc-pVQZ

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)