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	hartrees
Energy at 0K	-540.579052
Energy at 298.15K
HF Energy	-539.775048
Nuclear repulsion energy	108.171070

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	869	831	130.75	7.45	0.53	0.69
2	A₁	368	352	8.18	0.60	0.52	0.68
3	B₂	849	812	185.71	5.94	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.565
F2	1.197	-0.471
F3	-1.197	-0.471

	P1	F2	F3
P1		1.5829	1.5829
F2	1.5829		2.3932
F3	1.5829	2.3932

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: MP2=FULL/aug-cc-pVQZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: MP2=FULL/aug-cc-pVQZ

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)