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	hartrees
Energy at 0K	-840.146683
Energy at 298.15K
HF Energy	-838.367332
Nuclear repulsion energy	408.894524

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	820	784	0.00	13.31	0.00	0.00
2	A₁'	649	621	0.00	1.39	0.71	0.83
3	A₂"	973	931	408.72	0.00	0.00	0.00
4	A₂"	575	550	58.70	0.00	0.00	0.00
5	E'	1033	988	272.23	0.63	0.75	0.86
5	E'	1033	988	272.23	0.63	0.75	0.86
6	E'	533	510	40.94	0.38	0.75	0.86
6	E'	533	510	40.94	0.38	0.75	0.86
7	E'	173	165	0.06	0.21	0.75	0.86
7	E'	173	165	0.06	0.21	0.75	0.86
8	E"	513	490	0.00	0.61	0.75	0.86
8	E"	513	490	0.00	0.61	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.538	0.000
F3	1.332	-0.769	0.000
F4	-1.332	-0.769	0.000
F5	0.000	0.000	1.574
F6	0.000	0.000	-1.574

	P1	F2	F3	F4	F5	F6
P1		1.5380	1.5380	1.5380	1.5737	1.5737
F2	1.5380		2.6640	2.6640	2.2005	2.2005
F3	1.5380	2.6640		2.6640	2.2005	2.2005
F4	1.5380	2.6640	2.6640		2.2005	2.2005
F5	1.5737	2.2005	2.2005	2.2005		3.1475
F6	1.5737	2.2005	2.2005	2.2005	3.1475

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/aug-cc-pVQZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/aug-cc-pVQZ

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)