Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for SF₅Cl (sulfur chloropentafluoride)

using model chemistry: CISD/aug-cc-pV(T+d)Z

States and conformations

Geometric Data calculated at CISD/aug-cc-pV(T+d)Z

Point Group is C_4v

Cartesians (Å)

Atom	x (Å)	y (Å)	z (Å)
S1	0.000	0.000	-0.258
Cl2	0.000	0.000	1.774
F3	0.000	1.543	-0.274
F4	1.543	0.000	-0.274
F5	0.000	-1.543	-0.274
F6	-1.543	0.000	-0.274
F7	0.000	0.000	-1.798

Atom - Atom Distances (Å)

	S1	Cl2	F3	F4	F5	F6	F7
S1		2.0317	1.5434	1.5434	1.5434	1.5434	1.5401
Cl2	2.0317		2.5645	2.5645	2.5645	2.5645	3.5718
F3	1.5434	2.5645		2.1826	3.0866	2.1826	2.1687
F4	1.5434	2.5645	2.1826		2.1826	3.0866	2.1687
F5	1.5434	2.5645	3.0866	2.1826		2.1826	2.1687
F6	1.5434	2.5645	2.1826	3.0866	2.1826		2.1687
F7	1.5401	3.5718	2.1687	2.1687	2.1687	2.1687

More geometry information
Calculated Bond Angles

atom1	atom2	atom3	angle		atom1	atom2	atom3	angle
Cl2	S1	F3	90.612		Cl2	S1	F4	90.612
Cl2	S1	F5	90.612		Cl2	S1	F6	90.612
Cl2	S1	F7	180.000		F3	S1	F4	89.993
F3	S1	F5	178.777		F3	S1	F6	89.993
F3	S1	F7	89.388		F4	S1	F5	89.993
F4	S1	F6	178.777		F4	S1	F7	89.388
F5	S1	F6	89.993		F5	S1	F7	89.388
F6	S1	F7	89.388